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ELECTROCHEMISTRY AND ELECTROCHEMILUMINESCENCE OF [RU(II)-TRIS(BATHOPHENANTHROLINE-DISULFONATE)]4− IN APROTIC CONDITIONS AND AQUEOUS BUFFERS   Abstract In this work, the electrochemical and ECL properties of tris[1,10-phenanthrolinediyl-4,7-di(benzenesulfonate)] Ru(II) ([Ru(BPS)3]4-) have been addressed in both strictly aprotic conditions and aqueous buffers. A combined theoretical and experimental approach is presented to focus thermodynamics and kinetic effects of electro-generated species possessing highly […]